Table 2. Selectivity parameters for the target compounds
* retention times for all isomers ** internal standard compound
Name
RT
(min)
Quantifier Ion
Qualifier Ion 1
Qualifier Ion 2
Ion Ratio
(for qualifier ion 1/
qualifier ion 2)
[% of quant. ion]
Precursor
Mass
[m/z]
Product
Mass
[m/z]
Collision
Energy
[V]
Precursor
Mass
[m/z]
Product
Mass
[m/z]
Collision
Energy
[V]
Precursor
Mass
[m/z]
Product
Mass
[m/z]
Collision
Energy
[V]
Acephate
9.36
95.5
65.4
8
136.0
42.1
8
136.0
94.0
12
0.2 / 99
Acrinathrin 24.33 181.0
152.0
22
208.1
180.9
8
289.0
93.1
8
110 / 52
Amitraz
24.03 121.0
106.1
10
131.9
117.1
16
161.9
132.0
8
85 / 78
Azinphos-methyl
23.29 132.0
77.0
12
160.0
50.9
34
160.0
77.0
16
55 / 120
Azoxystrobin 30.33 344.1
156.0
34
344.1
171.9
36
344.1
329.0
14
100 / 250
Bifenthrin
22.08 165.1
163.6
24
181.0
165.9
10
181.0
179.0
12
3800 / 400
Bitertanol
25.25 170.0
115.1
34
170.0
141.1
20
170.0
169.1
16
140 / 40
Boscalid
(Nicobifen)
27.09 112.0
76.0
12
139.9
76.0
22
139.9
112.0
10
240 / 350
Bromopropylate 22.09 184.9
75.5
30
184.9
156.9
12
340.8
185.0
14
2500 / 600
Bromuconazole
21.87/
22.6*
172.9
74.0
38
172.9
109.0
26
172.9
144.9
16
100 / 150
Bupirimate
18.08 208.1
140.1
12
208.1
165.0
12
273.1
193.2
8
260 / 60
Buprofezin
18.08 105.1
50.9
32
105.1
77.0
18
175.0
132.1
12
275 / 75
Cadusafos
11.5
159.0
96.9
16
159.0
130.9
8
213.0
89.1
12
550 / 15
Captan
16.35 149.0
70.0
20
149.0
78.8
14
149.0
105.0
6
120 / 130
Carbaryl
14.13 115.0
89.0
16
144.0
115.1
22
144.0
116.1
10
800 / 400
Carbofuran 11.98 149.1
77.0
24
149.1
121.1
8
164.0
149.1
8
120 / 120
Carboxin
18.11
87.0
43.0
6
143.0
43.0
16
143.0
87.0
8
200 / 100
Chlorfenapyr
18.37 136.9
102.0
12
248.9
112.0
24
248.9
137.1
18
45 / 30
Chlorfenvinphos 16.13 266.9
159.0
16
266.9
203.0
10
323.0
266.9
14
25 / 80
Chlorobenzilate 18.89 111.0
75.1
14
139.0
74.9
26
139.0
111.0
12
215 / 440
Chlorothalonil
12.72 228.8
168.0
8
265.8
133.0
36
265.8
170.0
24
350 / 160
Chlorpropham 11.17 171.0
127.0
8
213.0
127.0
14
213.0
171.0
6
65 / 45
Chlorpyrifos-ethyl
14.88 196.7
107.0
36
196.7
168.9
12
313.9
257.9
12
240 / 135
Chlorpyrifos-
methyl
13.67 125.0
47.0
12
125.0
79.0
6
285.9
93.0
20
110 / 55
Cyfluthrin
26.67 163.0
65.1
26
163.0
91.1
12
163.0
127.1
6
100 / 25
Cyhalothrin 23.94 180.9
151.9
22
197.0
141.1
10
208.1
180.9
8
95 / 80
Cypermethrin
27.28/
27.53/
27.63/
27.72*
163.0
91.1
12
163.0
127.1
6
180.9
152.1
20
100 / 50
Cyproconazole 18.53 222.0
82.1
10
222.0
89.3
38
222.0
125.0
20
35 / 210
Cyprodinil
15.85 224.1
196.9
20
224.1
208.0
18
225.1
209.7
16
500 / 40
DDD p,p
19.16 235.0
165.1
20
235.0
199.0
14
236.8
165.0
20
21 / 48
DDE p, p
17.85 246.0
176.1
28
317.8
246.0
20
317.8
248.0
18
28 / 30
DDT p,p
20.39 235.0
165.1
22
235.0
199.5
10
236.8
165.0
22
1.5 / 48
Deltamethrin 30.04 181.0
152.1
22
252.8
92.9
16
252.8
172.0
8
40 / 35
Demeton-S-
methyl
10.91
88.0
59.8
6
109.0
79.0
6
141.9
79.0
12
10.1 / 25
Diazinon
12.51 137.1
54.1
20
137.1
84.1
12
179.1
121.5
26
170 / 10
8
15. Annex
Tables and Figures
