500 / 658
6
Table 2: Quantitation results for standards prepared in solvent
AVERAGE
AREA
Theobromine
Theophylline
234
Dyphylline
72
0.49 0.52% 427
1
2.40% 784
Caffeine
Chlorothiazine
75
0
24.53% 149
Cromolyn-Na 176
0.25 42.33% 456
1
1.28% 917
Hydroclorothiazide
255
Pemoline 102
0.34 18.81% 400
1
11.86% 780
Petoxifyline 793
-0.32 3.79% 4308
0
1.86% 8319
Dexamethasone
479
0
2.45% 1017
Boldenone 219
-0.01 14.44% 1261
0
1.97% 2471
Ketoprofen 315
0.60 7.64% 1191
1
9.43% 2381
Indomethacin
103
1
11.11% 212
Diclofenac
64
0.30 11.55% 281
1
8.84% 475
Flufenamic Acid 310
0.22 13.97% 892
1
2.52% 1780
Meclofenamic Acid
14
0.18 17.51% 61
1
41.26% 113
AVERAGE
AREA
AVERAGE
CALC.
CONC %RSD
AVERAGE
AREA
AVERAGE
CALC.
CONC %RSD
0.1 pg/µL
0.5 pg/µL
Theophylline (A)
1129
6
10.48% 2540
17
5.53% 5185
38 2.82% 45170
334 2.11%
Dyphylline (A)
9832
5
1.94% 22461
17
2.73% 44917
39 0.98% 322434
334 2.24%
Caffeine (A)
6330
6
6.86% 15401
18
4.94% 30016
37 2.14% 258749
336 1.20%
Chlorothiazine (A)
1798
7
5.99% 3834
17
5.48% 7967
37 0.94% 70426
334 1.24%
Hydroclorothiazide (A)
2487
7
3.07% 5684
18
2.05% 11276
38 2.02% 92748
331 1.39%
Pentoxifylline (A)
122524
-2
-6.01% 296023
16
3.35% 605430
49 2.36% 3152583
332 0.97%
Boldenone (A)
13426
7
2.77% 33942
19
1.55% 58628
35 2.21% 593649
334 1.24%
Ketoprofen (A)
19899
6
3.75% 43660
17
3.86% 88899
37 2.23% 754801
337 1.67%
Ketoprofen – MS
3
(A)
8097
4
4.05% 17578
15
2.82% 37039
40 2.09% 279306
339 1.97%
Indomethacin (A)
1087
2
28.26% 2382
13
6.78% 6442
48 4.05% 35792
332 2.61%
Diclofenac (A)
2577
3
2.37% 5355
13
5.46% 14471
46 4.62% 78597
332 2.94%
Meclofenamic Acid (A)
290
7
10.78% 447
10 22.75% 2130
44 2.92% 6086
122 16.84%
Cromolyn-Na (B)
11298
9
2.70% 30183
27
1.08% 88171
83 0.80% 698392
675 2.40%
Flufenamic Acid (B)
3442
15
3.59% 7763
21
1.84% 55407
88 2.44% 135790
200 13.92%
Theobromine (C)
6293
51
1.86% 17288
92
3.23% 51615
222 1.58% 471898 2009 0.77%
Table 3: Quantitation results for standards prepared in horse urine
AVERAGE
AREA
AVERAGE
CALC.
CONC %RSD
AVERAGE
AREA
AVERAGE
CALC.
CONC %RSD
AVERAGE
AREA
AVERAGE
CALC.
CONC %RSD
AVERAGE
AREA
AVERAGE
CALC.
CONC %RSD
3.3 pg/µL
16.6 pg/µL
41.6 pg/µL
333.3 pg/µL
20 pg/µL
100 pg/µL
250 pg/µL
2000 pg/µL
6.6 pg/µL
33.4 pg/µL
83.3 pg/µL
333.3 pg/µL