253 / 658
3
Table 3. SRM settings for the analytes and internal standards
Analyte
Precursor
Ion (
m/z
)
Quantifier
Ion (
m/z
)
Collision
Energy (V)
Qualifier
Ion (
m/z
)
Collision
Energy (V)
S-Lens
(V)
Amitriptyline
278.10
202.10
56
233.10
16
74
Bromazepam
316.11
182.10
31
209.10
26
95
Clobazam
301.10
259.10
20
224.10
32
90
Clomipramine
315.10
86.00
17
58.00
35
74
Clonazepam
316.00
270.10
25
214.00
37
101
Clozapine
327.10
270.10
23
192.00
42
94
Diazepam
285.10
193.10
32
154.00
27
88
Dothiepin
296.10
202.10
53
221.10
45
71
Doxepin
280.10
165.10
51
107.00
23
80
Flunitrazepam
314.10
268.10
26
239.10
34
92
Imipramine
281.20
86.00
16
58.00
35
69
Lamotrigine
256.00
211.00
26
109.00
49
89
Levetiracetam
171.10
126.10
14
69.00
28
36
Nitrazepam
282.10
236.10
24
207.10
34
97
Nortriptyline
264.20
233.20
13
91.10
32
66
Oxazepam
287.10
269.10
14
104.10
33
81
Perhexilline
278.20
95.10
28
67.00
34
87
Temazepam
301.11
255.10
22
283.10
13
72
Trimipramine
295.20
100.10
16
58.10
35
71
Internal Standards
Amitriptyline-D3
281.21
91.10
32
233.20
16
85
Clomipramine-D3
318.20
89.10
18
61.10
36
75
Clonazepam-D4
320.10
274.10
26
218.10
35
102
Clozapine-D4
331.20
272.20
25
192.10
45
102
Diazepam-D5
290.10
198.10
31
154.00
26
89
Doxepin-D3
283.20
107.00
23
77.00
46
78
Flunitrazepam-D7
321.10
275.20
26
246.20
35
96
Imipramine-D3
284.20
89.10
16
61.10
35
69
Lamotrigine-13C, 15N4
261.00
214.00
26
109.10
50
104
Levetiracetam-D6
177.10
132.20
14
69.10
30
38
Nitrazepam-D5
287.11
185.10
37
212.10
34
100
Nortriptyline-D3
267.20
91.00
33
233.20
14
66
Oxazepam-D5
292.10
246.10
22
274.10
15
84
Temazepam-D5
306.10
260.10
23
288.10
13
83
Trimipramine-D3
298.20
103.10
16
61.10
35
72