7
Appendix: List of pesticides with MRM transitions used (from [4])
Pesticide
Name
RT
(min)
Precursor
Mass
(
m/z
)
Product
Mass
(
m/z
)
Collision
Energy
(V)
Difluorobenzamid
Degradation (Isocyanat)
6.93 152.93
90.01
20
Difluorobenzamid
Degradation (Isocyanat)
6.93 152.93 125.01
20
Carbofuran 1
8.80 149.06 121.05
10
Carbofuran 1
8.80 164.08 149.07
10
Difluorobenzamid
Degradation
8.62 141.00
63.11
25
Difluorobenzamid
Degradation
8.62 141.00
113.09
15
Biphenyl-d10_ISTD
9.24 160.00 160.16
10
Biphenyl
9.28 154.08 153.08
15
Biphenyl
9.28 153.08 152.08
15
Carbofuran-3-hydroxy 1
10.43 137.05
81.01
18
Carbofuran-3-hydroxy 1
10.43 180.05
137.01
15
Tetrahydrophthalimid
10.84 151.04
79.01
25
Tetrahydrophthalimid
10.84 151.04 122.09
10
O-Phenylphenol
11.00 170.07
141.06
20
O-Phenylphenol
11.00 170.07
115.05
20
Molinate
11.10 187.10
126.07
10
Molinate
11.10 126.07
98.05
5
Chlorfenprop methyl
11.59 196.00 165.00
10
Chlorfenprop methyl
11.59 165.00 137.00
10
Fenobucarb
11.20 121.07
77.05
15
Fenobucarb
11.20 150.09 121.07
10
Propachlor
11.76 176.06 120.04
10
Propachlor
11.76 120.04
92.03
10
Propachlor
11.76 169.06 120.04
10
Propachlor
11.76 196.07 120.04
10
Cycloate
11.98 154.10
83.05
10
Cycloate
11.98 215.13
154.10
5
Diphenylamin
11.49 169.01 168.09
20
Diphenylamin
11.49 169.01 167.09
20
Chloropropham
12.26 213.06 127.03
15
Chloropropham
12.26 213.06 171.04
10
Phosmet-oxon
12.09 160.00 132.96
15
Phosmet-oxon
12.09 104.00
75.88
10
Phosmet-oxon
12.09 160.00
76.96
20
Prometon
13.10 225.16
183.13
10
Prometon
13.10 225.16
210.15
10
Carbofuran 2
13.13 149.06 121.05
10
Carbofuran 2
13.13 164.08 149.07
10
Profluralin
13.22 318.10
199.06
15
Profluralin
13.22 330.23 252.45
25
Swep
13.46 187.05 123.95
18
Swep
13.46 219.11
174.02
15
Trietazine
13.48 229.14
200.14
15
Trietazine
13.48 214.14
186.10
15
Dimethipin
13.53 117.98
57.97
10
Pesticide
Name
RT
(min)
Precursor
Mass
(
m/z
)
Product
Mass
(
m/z
)
Collision
Energy
(V)
Dimethipin
13.53 210.10
76.02
10
Terbutylazin
12.97 214.10 132.06
10
Terbutylazin
12.97 214.10 104.05
10
Propyzamid
13.04 173.01 145.01
15
Propyzamid
13.04 173.01 109.01
18
Propyzamid
13.04 175.02 147.01
15
Propyzamid
13.04 254.02 226.02
15
Isocarbamide
13.67 142.03
70.01
15
Isocarbamide
13.67 142.03 113.01
10
Dinoseb
13.92 211.13
116.99
15
Dinoseb
13.92 211.13
163.11
10
Terbazil
13.42 161.05
88.03
15
Terbazil
13.42 160.05
76.02
15
Bromocylen
14.37 358.79 242.85
15
Bromocylen
14.37 356.93 241.24
15
Dimethenamid
14.60 230.06 154.04
10
Dimethenamid
14.60 232.06 154.04
10
Dimethachlor
14.61 197.08 148.06
10
Dimethachlor
14.61 199.08 148.06
10
Acetochlor
14.65 174.11
146.15
15
Acetochlor
14.65 223.19
147.17
10
Desmetryn
14.68 213.11 171.08
10
Desmetryn
14.68 213.11
198.10
10
Flurprimidol
14.77 269.12 106.98
20
Flurprimidol
14.77 270.18 107.04
20
Alachlor
14.26 188.10 160.07
10
Alachlor
14.26 188.10
130.12
25
Alachlor
14.26 237.14
160.15
10
Metribuzin
14.14 198.08
82.03
20
Metribuzin
14.14 198.08
89.04
16
Propanil
15.00 217.01 161.00
10
Propanil
15.00 219.01 163.00
10
Fipronildesulfinyl
14.15 333.00 231.20
20
Fipronildesulfinyl
14.15 333.00 281.30
20
Carbofuran-3-hydroxy 2
15.02 137.05
81.01
18
Carbofuran-3-hydroxy 2
15.02 180.05 137.01
15
Prometryn
14.49 241.14
184.10
15
Prometryn
14.49 226.13 184.10
12
Tridiphan
15.18 186.94 158.94
15
Tridiphan
15.18 219.09 184.09
20
Ethofumesat
14.80 206.82 160.86
10
Ethofumesat
14.80 285.75 206.82
12
Pentanochlor
15.73 141.05 106.05
15
Pentanochlor
15.73 239.05 141.05
15
Chlorpyrifos
15.78 257.97 165.98
20
Chlorpyrifos
15.78 314.05 258.18
15
Bromacil
15.03 205.01 188.01
15
Bromacil
15.03 207.01 190.01
15