References
[1] Robert K. Boyd, Cecilia Basic, Robert A. Bethem,
Trace Quantitative Analysis by Mass Spectrometry,
2008 John Wiley & Sons, Ltd.
[2] Material Safety Data Sheet NDMA.
[3] Agency for Toxic Substances & Disease Registry,
Public Health Statement for n-nitrosodimethylamine,
1989,
.
html
[4] Richard A. Scanlan, Nitrosamines and Cancer, Linus
Pauling institute,
/
nitrosamine.html .
[5] Mario M. Mangino and Richard A. Scanlan,
N-Nitrosamines in Beer, N-Nitroso Compounds,
ACS Symposium Series, Vol. 174, 1981, Chapter 17,
229–245.
[6] Munch, J.W., Bassett, M.V. Method 521:
Determination of nitrosamines in drinking water
by solid phase extraction and capillary column gas
chromatography with large volume injection and
chemical ionization tandem mass spectrometry (MS/
MS) (Version 1.0) U.S. Environmental Protection
Agency.
[7] Raymond E. March, Richard J. Hughes, Quadrupole
Storage Mass Spectrometry, 2nd Ed., John Wiley &
Sons 1989.
[8] AOAC Official Method 982.11, 2000.
[9] Introducing AutoSRM, Thermo Fisher Scientific,
Technical Brief No. AB52298, 2012.
[10] Thermo Scientific TSQ 8000 Triple Quadrupole
GC-MS/MS Instrument Method, Thermo Fisher
Scientific, Technical Brief No. AB52299, 2012.
Technical Support Note-000
Thermo Fisher Scientific,
San Jose, CA USA is ISO Certified.
thermoscientific.com
©2012 Thermo Fisher Scientific Inc. All rights reserved. Bio-Beads is a registered trademark of Bio-Rad Laboratories, Inc. ISO is a trademark of the International
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intellectual property rights of others. Specifications, terms and pricing are subject to change. Not all products are available in all countries. Please consult your
local sales representative for details.
Africa-Other
+27 11 570 1840
Australia
+61 2 8844 9500
Austria
+43 1 333 50 34 0
Belgium
+32 53 73 42 41
Canada
+1 800 530 8447
China
+86 10 8419 3588
Denmark
+45 70 23 62 60
Europe-Other
+43 1 333 50 34 0
Finland /Norway/Sweden
+46 8 556 468 00
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+33 1 60 92 48 00
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+49 6103 408 1014
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+91 22 6742 9434
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+1 608 276 5659
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+31 76 579 55 55
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+34 914 845 965
Switzerland
+41 61 716 77 00
UK
+44 1442 233555
USA
+1 800 532 4752
AN52291_E 05/12S
Application Note 52291
Pesticide
Name
RT
(min)
Precursor
M ss
(
m/z
)
Product
Mass
(
m/z
)
Collision
Energy
(V)
Azinphosmethyl
22.95 160.00 132.00
10
Azinphosmethyl
22.95 160.00 104.64
10
Pyriproxyfen
23.06 136.00
77.92
20
Fenamirol
23.55 251.02 139.01
15
Fenamirol
23.55
Pyridaben
24.50 364.14 309.12
5
Pyridaben
24.50 309.12 147.06
15
Fluquinconazol
24.59 340.01
Fluquinconazol
24.59 342.01 300.01
22
Etofenprox
26.05 163.09 107.06
16
Etofenprox
26.05 163.09 135.07
10
Etofenprox
26.05 376.14 135.02
30
Etofenprox
26.05 376.14 163.09
10
Silafluofen
26.25 179.00 151.00
7
Silafluofen
26.25 286.13 258.12
15
Difenconazol 1
26.91 323.05 265.04
15
Difenconazol 1
26.91 325.05 267.04
20
Difenconazol 2
27.05 323.05 265.04
15
Difenconazol 2
27.05 325.05 267.04
20
Indoxacarb
28.55 264.02 176.14
10
Indoxacarb
28.55 264.02 148.03
20
Indoxacarb
28.55 321.05 289.34
10
Thermo Fisher
Scientific,Austin,TX
USA is ISO Certified.
Thermo Fisher Scientific,
San Jose, CA USA is ISO Certified.
thermoscientific.com
©2012 Thermo Fisher Scientific Inc. All rights reserved. Bio-Beads is a registered trademark of Bio-Rad Laboratories, Inc. ISO is a trademark of the International
Standards Organization. All other trademarks are the property of Thermo Fisher Scientific Inc. and its subsidiaries. This information is presented as an example
of the capabilities of Thermo Fisher Scientific Inc. products. It is not intended to encourage use of these products in any manners that might infringe the
intellectual property rights of others. Specifications, terms and pricing are subject to change. Not all products are available in all countries. Please consult your
local sales representative for details.
Africa-Other
+27 11 570 1840
Australia
+61 2 8844 9500
Austria
+43 1 333 50 34 0
Belgium
+32 53 73 42 41
Finland /Norway/Sweden
+46 8 556 468 00
France
+33 1 60 92 48 00
Germany
+49 6103 408 1014
Middle East
+43 1 333 50 34 0
Netherlands
+31 76 579 55 55
South Africa
+27 11 570 1840
Spain
+34 914 845 965
Pesticide
Name
RT
(min)
Precursor
Mass
(
m/z
)
Product
Mass
(
m/z
)
Collision
Ene gy
(V)
Azinphosmethyl
22.95 160.00 132.00
10
Azinphosmethyl
22.95 160.00 104.64
10
136.00
77.92
20
Fenamirol
23.55 251.02 139.01
15
Fenamirol
23.55 330.03 139.01
10
Pyridaben
24.50 364.14 309.12
5
Pyridaben
24.50 309.12 147.06
15
Fluquinconazol
24.59 340.01 298.01
22
Fluquinconazol
24.59 342.01 300.01
22
Etofenprox
26.05 163.09 107.06
16
Etofenprox
26.05 163.09 135.07
10
Etofenprox
26.05 376.14 135.02
30
Etofenprox
26.05 376.14 163.09
10
Silafluofen
26.25 179.00 151.00
7
Silafluofen
26.25 286.13 258.12
15
Difenconazol 1
26.91 323.05 265.04
15
Difenconazol 1
26.91 325.05 267.04
20
Difenconazol 2
27.05 323.05 265.04
15
Difenconazol 2
27.05 325.05 267.04
20
Indoxacarb
28.55 264.02 176.14
10
Indoxacarb
28.55 264.02 148.03
20
Indoxacarb
28.55 321.05 289.34
10
Thermo Fisher
Scientific,Austin,TX
USA is ISO Certified.
Thermo Fisher Scientific,
San Jose, CA USA is ISO Certified.
thermoscientific.com
©2012 Thermo Fisher Scientific Inc. All rights reserved. Bio-Beads is a registered trademark of Bio-Rad Laboratories, I
Standards Organization. All other trademarks are the property of Thermo Fisher Scientific Inc. and its subsidiaries. This i
of the capabilities of Thermo Fisher Scientific Inc. products. It is not intended to encourage use of these products in any
intellectual property rights of others. Specifications, terms and pricing are subject to change. Not all products are availab
local sales representative for details.
Africa-Other
+27 11 570 1840
Australia
+61 2 8844 9500
Austria
+43 1 333 50 34 0
Belgium
+32 53 73 42 41
Canada
+1 800 530 8447
China
+86 10 8419 3588
Denmark
+45 70 23 62 60
Finland /Norway/Sweden
+46 8 556 468 00
France
+33 1 60 92 48 00
Germany
+49 6103 408 1014
India
+91 22 6742 9434
Italy
+39 02 950 591
Japan
+81 45 453 9100
Middle
Netherl
South A
Spain
+
Switzer
UK
+44
USA
+1
Pesticide
Name
RT
(min)
Precursor
Mass
(
m/z
)
Product
Mass
(
m/z
)
Collision
Energy
(V)
Azinphosmethyl
22.95 160.00 132.00
10
Azinphosmethyl
22.95 160.00 104.64
10
Pyriproxyfen
23.06 136.00
77.92
20
Fenamirol
23.55 251.02 139.01
15
enamirol
23.55 330.03 139.01
10
Pyridaben
24.50 364.14 309.12
5
Pyridaben
24.50 309.1
147.06
15
Fluquinconazol
24.59 340.01 298.01
22
Fluquinconazol
24.59 342.01 300.01
22
Etofenprox
26.05 163.09 107.06
16
Etofenprox
26.05 163.09 135.07
10
Etofenprox
26.05 376.14 135.02
30
Etofenprox
26.05 376.14 163.09
10
Silafluofen
26.25 179.00 151.00
7
Silafluofen
26.25 286.13 258.12
15
Difenconazol 1
26.91 323.05 265.04
15
Difenconazol 1
26.91 325.05 267.04
20
Difenconazol 2
27.05 323.05 265.04
15
Difenconazol 2
27.05 325.05 267.04
20
Indoxacarb
28.55 264.02 176.14
10
Indoxacarb
28.55 264.02 148.03
20
Indoxacarb
28.55 321.05 289.34
10
Thermo Fisher
Scientific,Austin,TX
USA is ISO Certified.
AN10315_E 02/13S
©2012 Thermo Fisher Scientific Inc. All rights reserved. Bio-Beads is a registered trademark of Bio-Rad
Laboratories, Inc. ISO is a trademark of the International Standards Organization. All other trademarks are the
property of Thermo Fisher Scientific Inc. and its subsidiaries. This information is presented as an example of the
capabilities of Thermo Fisher Scientific Inc. products. It is not intended to encourage use of these products in any
manners that might infringe the intellectual property rights of others. Specifications, terms and pricing are subject to
change. Not all products are available in all countries. Please consult your local sales representative for details.
thermoScientific.com
