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7

Location

Haulover

Boat

Ramp

Haulover

Marina

Dinner Key Marina

Bayfront

Park

Pelican

Harbor

Park

FIU

Campus

Beach

Miami Beach Marina

Latitude N

25.91684 25.90613

25.7272

25.77274 25.84713 25.90994

25.77194

Longitude W

80.12383 80.12396

80.23767

80.18491 80.16782 80.1364

80.14027

PAH

MDL

(ng/L)

RL

(ng/L)

Measured

Conc

(ng/L)

Measured

Conc

(ng/L)

Measured

Conc

(ng/L)

Duplicate

(ng/L)

Ave±

σ

(ng/L)

Measured

Conc

(ng/L)

Measured

Conc

(ng/L)

Measured

Conc

(ng/L)

Measured

Conc

(ng/L)

Measured

Conc in

Fortified

Matrix

Experiment

(ng/L)

Fortification

Level

(ng/L)

%

Rec

Acenaphthene 15

45

-

-

-

-

-

-

-

-

184

176

104

Acenaphthylene 16

49

-

-

-

-

-

-

-

-

179

176

102

Antracene

29

86

-

-

-

-

-

-

-

-

179

176

101

Benz[

a

]

anthracene

12

36

-

-

-

-

-

-

-

-

160

176

91

Benzo[

b

]

fluoranthene,

perylene

34 102

-

-

-

-

-

-

-

-

370

373

99

Benzo[

g,h,i

]

perylene

19

57

-

-

-

-

-

-

-

-

185

176

105

Benzo[

k

]

fluoranthene

21

63

-

-

-

-

-

-

-

-

189

176

108

Crysene

11

33

-

-

-

-

-

-

-

-

173

176

98

Dibenz[

a,h

]

anthracene

16

48

-

-

-

-

-

-

-

-

188

176

107

Fluoranthene

12

36

-

-

-

-

-

-

-

-

180

176

101

Fluorene

7.9

24

-

-

-

-

-

-

-

-

187

176

106

Indeno[1,2,3-

cd

]pyrene

26

78

-

-

-

-

-

-

-

-

197

176

112

Naphthalene

20

60

101

-

104

100 102±2

-

-

-

-

189

176

107

C1-

naphthalenes

13

40

129

-

74

76

75±1

-

-

-

-

419

353

119

C2-

naphthalenes

15

44

<RL

-

47

45

46±1

-

-

-

-

177

176

101

Phenanathrene 19

57

-

-

-

-

-

-

-

-

167

176

94

Pyrene

17

50

-

-

-

-

-

-

-

-

166

176

94

Total PAH

230

0

225

221

223±2

0

0

0

0

% Recovery

Average

103±7

Table 2. Method performance upon analysis of surface seawater of US EPA priority PAHs.

− Below MDL